In-situ deposition of silver nanoparticles on cuprous oxide hollow spheres for sensitive and recyclable SERS sensing in solution based on electromagnetic and chemical enhancement

Abstract

In order to achieve widespread application of surface-enhanced Raman spectroscopy (SERS) technique for practical sensing illegal additives in food, it is crucial to construct a reliable SERS substrate that offers both high sensitivity and reusability. This work utilized a simple and rapid in-situ deposition method to deposit Ag nanoparticles onto hollow Cu2O nanospheres, resulting in the formation of Cu2O/Ag nanocomposites with photocatalytic and SERS properties. These nanocomposites were employed as a hopeful SERS analysis for effective sensing of colorant additives in fruit juice, including methylene blue (MB) and rhodamine 6G (R6G). Impressively, the nanocomposites exhibited an exceptional detection limit of 10−9 M for the color agents and demonstrated a strong linear relationship between SERS intensities and the logarithmic concentration (R2 ≥ 0.95). The hollow structure of Cu2O provided low density and long-term dispersion stability in solution, which are beneficial for real-time monitoring the additives in liquid food. The excellent SERS performance can be attributed to the electromagnetic effect of Ag metals and the chemical enhancement of Cu2O semiconductors, as confirmed by the N 1 s XPS spectra from MB. Furthermore, the Cu2O/Ag nanocomposites efficiently degraded dye molecules under UV light irradiation within a short period of 45 min. So, the nanocomposites exhibited practical recyclability, as demonstrated by their consistent performance over five cycles of SERS sensing. These findings highlight their significant potent for SERS sensing trace pollutants and ecological restoration by photocatalytic reaction in the future.