Improving the interlaminar bonding and thermal conductivity of polymer composites by using split-radial mesophase pitch-based carbon fiber as reinforcement

Abstract

Mesophase-pitch-based carbon fiber (MPCF) reinforced polymer (MPCFRP) have excellent properties such as high thermal conductivity and high modulus, but the significant anisotropy and surface inertness of MPCF result in the poor interlaminar thermal conductivity and interface bonding of MPCFRP, which greatly limits its application. To address this issue, MPCF-A with split-radial structure was prepared through fiber structure modulation. Compared with the conventional skin-core fiber (MPCF-B), the higher surface roughness and chemical activity of MPCF-A contribute to stronger mechanical locking and chemical bonding between fibers and resin, meanwhile open wedge crack and better graphite microcrystalline structure of MPCF-A play a positive role in increasing the contact points and reducing the phonon scattering in the heat transfer. Therefore, the interlaminar shear strength (40.7 MPa) and interlaminar thermal conductivity (2.09 W/(m·K)) of MPCFRP-A are 9.12% and 27.4% higher than those of MPCFRP-B, respectively, on the basis of the excellent in-plane thermal conductivity (322.8 W/(m·K)). This study provides a reliable guide to improve the interlayer performance of MPCFRP by tailoring the fiber microstructure.