Improving the efficiency of thin-film fiber-shaped dye-sensitized solar cells by using organic sensitizers

Abstract

Fiber-shaped Dye-Sensitized Solar Cells (DSSFs) represent one of the most interesting technologies aimed at the light harvesting and the production of electricity for wearable applications. In order to boost DSSFs commercialization, their production costs and environmental impact must be reduced. To this end, a suitable strategy could be to build thin film-based devices endowed with metal-free organic sensitizers, exploiting their higher molar extinction coefficients compared to typical ruthenium-containing organometallic dyes. In this work, three thiazolo[5,4-d]thiazole-based organic dyes, TTZ3, TTZ5 and TTZ7, capable of strongly absorb visible light, were used for the first time to manufacture titanium wire-based DSSFs. DSSFs based on a thin TiO2 layer (5 μm) sensitized with the three organic dyes were prepared and tested and the obtained results show that power conversion efficiencies for the organic dyes (0.80%) are higher than that obtained with the reference N719 dye (0.45%). An efficiency of 0.99% with short circuit current density equal to 3 mA/cm2 was achieved when the TTZ7-based DSSFs were tested in diffuse illumination condition, highlighting the supremacy of these dyes compared to the metal-organic reference. The excellent photovoltaic performances of TTZ dyes were attributed to their better light harvesting properties, resulting in the production of higher photocurrent densities, which was confirmed by the electrochemical impedance spectroscopy (EIS) analysis. The superiority of organic dyes on DSSFs performances compared to N719, shown for the first time in this work, support the real possibility to apply these molecules for the preparation of efficient light-harvesting devices based on thin film photoanodes.