Improvement of luminescence properties of NaYF4 :Yb3+ /Er3+ upconversion materials by a cross-relaxation mechanism based on co-doped Ho3+ ion concentrations.

Abstract

NaYF4 :Yb3+ /Er3+ /Ho3+ nanophosphors were successfully synthesized using a solvothermal method and with various concentrations of Ho3+ ions. The crystal structure, grain size, morphology, and luminescence properties were analyzed by X-ray diffraction, field-emission scanning electron microscopy, and photoluminescence measurements. All samples were crystallized as a cubic structure; it was confirmed that all samples exhibited strong green emission and weak red emission generated at a particular level of the activated ions. The strongest upconversion fluorescence intensity was observed in the Ho3+ and Er3+ ions co-doped NaYF4 materials with a Ho3+ ion concentration of 0.005 mol. Only the green fluorescence intensity at the 542 nm centre increased strongly due to the 4 S3/2 →4 I15/2 energy transfer. This increase in upconversion fluorescence intensity at a selected wavelength was described as a cross-relaxation mechanism due to the addition of Ho3+ ions.