Abstract

TaOX is one of the most promising switching materials for resistive random access memory (RRAM) due to its excellent endurance. In this letter, the TaOX-based RRAM devices with three different electrode structures were designed and fabricated to reduce its operating voltage and improve its uniformity. The ITO/TaOX/TiN device could maintain more than ∼104 cycles with high uniformity in low operating voltage (the mean voltages of set and reset were 0.036 V and −0.109 V, respectively), which could be attributed to the oxygens-rich property of ITO electrode and the TiON layer (the naturally formed layer when the TiN layer contacted with oxygens). According to X-ray photoelectron spectroscopy (XPS) characterizations and electrical results, a switching mechanism based on oxygen vacancies concentration gradient was proposed to explain the TaOX-based ultralow operating voltage RRAM device.

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