Abstract
Ionic conductivity of La3+ and Mg2+ co-doped ceria, synthesized by auto-combustion method, is investigated here as electrolytes for intermediate-temperature solid oxide fuel cells (IT-SOFCs, operating below 800 °C). The prepared nanocrystalline electrolytes, LMDC10 (Ce0.9La0.05Mg0.05O2-δ) and LMDC20 (Ce0.8La0.1Mg0.1O2-δ) have exhibited improved ionic conductivities of 1.31 × 10−2 and 1.39 × 10−1 S cm−1 at 1073 K with reduced activation energies of 0.93 and 0.97 eV, respectively, when compared to conventional electrolytes like yttria-stabilized zirconia. The prepared samples are characterized by XRD, Raman spectra, XPS and FESEM which confirmed the formation of single-phasic cubic fluorite structure. Thus, the potential for La3+ and Mg2+ co-doped ceria electrolytes to offer cost-effective alternatives with low sintering temperatures and high performance for IT-SOFCs.
Published Version
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