Imbibition and structure of silica nanoporous media characterized by neutron imaging

Abstract

HypothesisColloidal silica dispersions dried under controlled conditions form solid gels that display mechanical properties similar to those observed in several practical processes. An understanding of their structural characteristics and liquid flow properties can therefore help establish these gels as an alternative family of model materials to study practical porous systems. ExperimentsNeutron radiography is a non-destructive technique well-adapted to study hydrogen-rich domains in porous materials due to the high attenuation power of hydrogen. We apply this technique to study gels prepared from silica nanoparticles of radii 5–40 nm. FindingsThe water content in the gels have been quantified and different types of porosities have been determined: total porosity, effective porosity that contributes to liquid flow, and residual porosity that contains bound residual water. This residual water increases with decrease in particle size and constitutes an important fraction of the gel. The dynamics of water imbibition follows a √t law, from which the effective pore size and permeability are evaluated. We highlight the role of particle size on water retention, on particle organization and its impact on mechanical resistance. Quantitative analysis of the propagating liquid front shows front broadening that suggests elongated pores with reduced correlated liquid menisci.