Abstract
The formation and oxidation of the methanol adsorbate at platinum in acid solutions is performed under potential control using a flow cell technique. The charges in both processes are equal; this fact confirms the results of Podlovchenko et al. obtained from charging curves after open circuit adsorption. It is shown, using the on-line MS technique and labelled methanol, CD 3OH, that the adsorbed intermediate is probably COH.
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