Abstract
The degradation of aqueous diethanolamine (DEA) solutions due to carbonyl sulphide (COS) was studied by contacting the solutions (10–40 wt. %) in a well stirred, 600-ml stainless-steel autoclave with COS-nitrogen mixtures at temperatures ranging from 120 to 180°C. Combined gas chromatography-mass spectrometry, melting point determinations and elemental and infrared analyses were used to identify most of the major reaction products, viz., monoethanolamine, ethylaminoethanol, ethyldiethanolamine, hydroxyethylacetamide, hydroxyethylpiperazine, ethanethioic acid S-hydroxyethylaminomethyl ester, bis(hydroxyethyl)ethylenediamine, bis(hydroxyethyl)piperazine, hydroxyethyloxazolidone, hydroxyethylimidazolidone, tris(hydroxyethyl)ethylenediamine, bis(hydroxyethyl)imidazolidone, acetaldehyde, acetone, butanone, acetic acid, ethanol, diethyl disulphide, dithiane and pyridines. In addition, a solid product containing sulphur was formed. The practical implications of the studies for gas plant operators are discussed.
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