Abstract
The calculation of ideal gas thermodynamic properties for steam to 10,000 K is examined. Centrifugal effects are included using spectroscopic data for the lowest vibrational levels, with extension to higher bending levels based on estimates from a bending model. Modifications are examined for rotational and vibrational cut-off effects. Uncertainties in obtaining a suitably regularized representation of energy versus bond stretching vibration in approaching the dissociation energy region appear relevant to the reliability of the extrapolation.
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Schedule a callMore From: Journal of research of the National Institute of Standards and Technology
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