Abstract

ICP (Inductively Coupled Plasma) analyses of the Cretaceous marine sandstones at the Azogues (Loma Guashon), Ecuador cinnabar-mercury occurrence gave 11 - 113 ppm Hg. However, the ancient Azogues mines have been well documented previously, for example: 1) a 1799 hand drawn map “Plan del Cerro Mineral de Azogue” shows numerous adits; 2) during Colonial time, Cuenca founder, Gil Ramirez Davalos was owner of the mercury mines; 3) in the late 1800s, Teodoro Wolf described well-worked adits at Guashon and samples with 0.5% Hg; and more recently, 4) the Metallogenic Map of Ecuador shows the mercury occurrence at Azogues. Mineral resource assessment of the Azogues occurrence is important to regional archaeological studies of resource availability and ancient use of cinnabar as a pigment and as a source of mercury for gold amalgamation before the arrival of the Europeans, and possibly later, for silver amalgamation, during Colonial time.

Highlights

  • In Latin America, Spanish mercury is preferred for small-scale gold mining and azogue, with its hint of Spanish origin and supposed higher quality, commands a higher price than recycled local mercury or mercury produced in the U.S or elsewhere

  • Small pits in the Sind (Indus) Riverbed were filled with mercury; the mercury amalgamated the alluvial gold flakes and the mercury-gold amalgam was recovered, squeezed in a cloth to remove most of the mercury, and the amalgam “nugget” was burned to volatilize any remaining mercury

  • Cinnabar and mercury were known and used for only two purposes in the pre-Columbian Andes and mercury was essential to Colonial silver processing

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Summary

Introduction

Mercury and cinnabar occurrences are known throughout the Andes and blood-red cinnabar (HgS), the ore of mercury, was mined, selectively sorted, and ground for use as a pigment (vermilion), in funeral rituals, and as makeup during pre-contact time (Whitaker, 1941; Petersen, 1970/2010; Brown, 2001; Brooks et al, 2008). Perú produced 16-22 metric tons of gold from small-scale alluvial gold mining, using mercury, during 2007-2011 (Gurmendi, 2012). As another example of the importance of mercury in alluvial gold mining, approximately 26,000,000 pounds (or 342,000 seventy-six pound flasks) of mercury were used during the California Gold Rush in 1849-50 (Alpers et al, 2005)

Azogue and Mercury
Regional Mercury Occurrences
Previous Work
ICP Data from Azogues
History of Retorting and Ancient Industrial Uses
Human Health
Conclusion

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