Abstract

(Diacetoxyiodo) benzene (DAIB) oxidizes papaverine to papaveraldine (2) and to 1-hydroxymethyl-6, 7-dimethoxyisoquinoline (3), whereas 3′ -desmethylpapaverine and 6-desmethylpapaverine are converted into novel products (4) and (5), respectively.

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