Abstract
The on-line, self-powered monitoring of the organic carbon content in hypersaline solutions (e.g. chemical oxygen demand, COD) based on a microbial biosensor would avoid the generation of toxic waste, originated by common COD analytical methods, and reduce the release of pollutants into the environment. Herein, a disposable cathode was applied to microbial fuel cells (MFCs) for the environmental friendly monitoring of the COD reaching a sensitivity one order of magnitude higher compared to the MFC with an air breathing cathode. Additionally, the entrapment of bacterial cells in alginate-capsules ensured a considerable linear range (up to approximately 10,000 mg COD L−1), providing opportunities for the wide application of the device to hypersaline solutions characterized by different origins and contamination levels.
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