Hygroskopische Langzeiteigenschaften von Polypropylen basierten Verbundwerkstoffen mit und ohne organisch modifiziertem Ton

Abstract

Recycled PP contains various impurities and has poor and variable mechanical properties compared to virgin PP. This, in general, rules out the use of recycled PP in the original applications and in other high-value applications. Hence, this study investigated the effects of polymer matrix type, weight fraction of wood flour and organoclay on the thickness swelling and water absorption behavior of PP based hybrid composites. WPCs based on polypropylene (virgin and recycled), wood flour, organoclay and maleated polypropylene (MAPP) were made using melt compounding and subsequent injection molding. Composites made from recycled polypropylene (rPP) exhibited better dimensional stability compared to the virgin (vPP) based ones. Besides, wood flour did not completely encapsulate in the polymer matrix at 50 % weight fraction. Incorporation of nanoclay exhibited a beneficial effect on both the water absorption and thickness swelling by creating a tortuous path as a result of its characteristic barrier property. The improvements in hygroscopic characteristics of hybrid composites using rPP and nanoclay were further supported by scanning electron microscopy and X-ray diffraction methods. Conclusively, PP recycled from post-consumer applications can be used in value-added composites without accepting the expense of separating out impurities from the polymer.