Hydrotreating of gas oil on SBA-15 supported NiMo catalysts

Abstract

The siliceous and the metal substituted (B or Al)-SBA-15 molecular sieves were used as a support for NiMo hydrotreating catalysts (12 wt.% Mo and 2.4 wt.% Ni). The supports were characterized by X-ray diffraction (XRD), scanning electron microscopy and N 2 adsorption–desorption isotherms. The SBA-15 supported NiMo catalysts in oxide state were characterized by BET surface area analysis and XRD. The sulfided NiMo/SBA-15 catalysts were examined by DRIFT of CO adsorption and TPD of NH 3. The HDN and HDS activities with bitumen derived light gas oil at industrial conditions showed that Al substituted SBA-15 (Al-SBA-15) is the best among the supports studied for NiMo catalyst. A series of NiMo catalysts containing 7–22 wt.% Mo with Ni/Mo weight ratio of 0.2 was prepared using Al-SBA-15 support and characterized by BET surface area analysis, XRD and temperature programmed reduction and DRIFT spectroscopy of adsorbed CO. The DRIFT spectra of adsorbed CO showed the presence of both unpromoted and Ni promoted MoS 2 sites in all the catalysts, and maximum “NiMoS” sites concentration with 17 wt.% of Mo loading. The HDN and HDS activities of NiMo/Al-SBA-15 catalysts were studied using light gas oil at temperature, pressure and WHSV of 370 °C, 1300 psig and 4.5 h −1, respectively. The NiMo/Al-SBA-15 catalyst with 17 wt.% Mo and 3.4 wt.% of Ni is found to be the best catalyst. The HDN and HDS activities of this catalyst are comparable with the conventional Al 2O 3 supported NiMo catalyst in real feed at industrial conditions.