Abstract
A polyoxometalate-based complex [Cu I (phen)2]4[HPW11.5 VI Cu0.5 II O40] (1) (phen = 1,10-phenathroline) has been synthesized by hydrothermal method and characterized by IR, elemental analysis, TG technique and X-ray crystallography. [Cu I (phen)2]+ ion balances the charge on the α-Keggin [HPW11.5 VI Cu0.5 II O40]4 − anion. The cooperativity of intermolecular π −π stacking, C─H… π interactions and C─H… O hydrogen bonds link the ions together to form a three-dimensional chiral structure. The luminescent properties of the title complex in the solid state were investigated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
