Abstract
A new organically directed iron sulfate (C 6N 2H 14)[Fe(SO 4) 2(OH)]·H 2O with zigzag chains has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy and thermo-gravimetric analysis. The compound crystallizes in monoclinic space group C2/ c, crystal data: a = 18.6419(18) Å, b = 12.0129(12) Å, c = 12.4794(12) Å, β = 108.275(2), V = 2653.7(4) Å 3, Z = 8, M = 395.17. The inorganic moiety of the title compound is constructed from the tancoite-type unit via the linking fashion of hydroxyl groups with trans– cis positions, leading to a novel zigzag { Fe O Fe } chain, which is isomeric with two analogousness reported by us. An interesting transformation between the 1D iron–sulfate chains to its isomers via changing the specific organic amines was also performed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
