Abstract
Using the hydrothermal conditions, a novel porous Co(II) formate framework with N2H5+ cations, {[N2H5+][Co(HCOO)3]}n (1) has been isolated and characterized by single crystal X-ray diffraction analysis and thermal gravimetric analysis. The crystal crystallizes in the Rhombohedral R-3 space group, a = 8.2059(17) Å, b = 8.2059(17) Å, c = 22.165(5) Å, γ = 120o, and Z = 2. These formate ligands adopt the bi-dentate bridging coordination modes to link neighboring Co(II) ions forming a 3D porous framework. The coordinated formate ligands and free N2H5+ cations were obtained via the decomposition of diformylhydrazine under the hydrothermal conditions. The result also reveals a new example of the construction of these highly dimensional porous cobalt(II) formate frameworks using hydrothermal synthetic techniques.
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