Abstract

The hydrothermal conversion of Na-magadiite in tetramethylammonium hydroxide (TMAOH) and 1,4-dioxane to form a new layered silicate structure, assigned as KLS1, is described. Total conversion of Na-magadiite to KLS1 was achieved in a short reaction time of 4 hours. The nature of the new silicate structure was characterized by using 29Si MAS NMR and found to contain predominantly Q3 type (SiO)3–Si–OH building units.

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