Abstract
The first examples of the hydrophosphination of alkyl vinyl sulfides and selenides are described. The reaction of secondary phosphines (R 1 ) 2 PH 1-3 with vinyl chalcogenides CH 2 =CHXR 2 4-9 proceeds readily under radical initiation to give in anti-Markovnikov mode regiospecifically the corresponding organylchalcogenophosphines (R 1 ) 2 PCH 2 CH 2 XR 2 10a-h in high yields.
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