Abstract

The hydrophobicity and anti-fouling properties of materials have important application value in industrial and agricultural production and people’s daily life. To study the relationship between the unit width L0 of the parabolic hydrophobic material and the hydrophobicity and anti-fouling properties, the rough surface structure of the parabolic with different widths was prepared by grinding with different SiC sandpapers, and further, to obtain hydrophobic materials through chemical oxidation and chemical etching, and modification with stearic acid (SA). The morphology, surface wetting and anti-fouling properties of the modified materials were characterized by SEM and contact angle measurement. The oil–water separation performance and self-cleaning performance of the materials were explored. The surface of the modified copper sheet forms a rough structure similar to a paraboloid. When ground with 1500 grit SiC sandpaper, it is more conducive to increase the hydrophobicity of the copper sheet surface and increase the contact angle of water droplets on the copper surface. Additionally, the self-cleaning and anti-fouling experiments showed that as L0 decreases, copper sheets were less able to stick to foreign things such as soil, and the better the self-cleaning and anti-fouling performance was. Based on the oil–water separation experiment of copper mesh, the lower L0 has a higher oil–water separation efficiency. The results showed that material with parabolic morphology has great self-cleaning, anti-fouling, and oil–water separation performance. The smaller the L0 was, the larger the contact angle and the better hydrophobic performance and self-cleaning performance were.

Highlights

  • Infiltration in life can be seen everywhere, for example, the excess energy consumed by a ship sailing due to hydraulic friction [1]

  • The copper mesh and copper sheets were applied to oil–water separation, anti-fouling, and self-cleaning experiments, which showed that the parabolic morphology has great hydrophobic and anti-fouling properties

  • By controlling grinding, chemical etching, oxidation, and modifying conditions, the parabolic structure can be obtained on the surface of the copper sheets and copper mesh

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Summary

Introduction

Infiltration in life can be seen everywhere, for example, the excess energy consumed by a ship sailing due to hydraulic friction [1]. Interest in super-hydrophobic surfaces has increased in recent years [2,3,4,5,6]. Hydrophobicity and stain resistance are widely used in many areas such as anti-biofouling surfaces in a marine environment [7,8,9,10], fluid drag reduction [11,12], anti-contamination surfaces of windows for buildings and automobiles [13,14,15], microfluid [16,17], and many others. Studying hydrophobicity and stain resistance is important in industry, agriculture, and people’s daily life. To obtain excellent hydrophobic and anti-fouling materials, scholars constantly explore the prediction theory of the superhydrophobic model and the preparation technology. Nishino et al [18]

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