Hydrolytically stable mixed ditopic linker based zirconium metal organic framework as a robust photocatalyst towards Tetracycline Hydrochloride degradation and hydrogen evolution

Abstract

In the existing eco-crisis, designing and engineering an efficient as well as water stable photocatalyst for energy conversion and pollutant abatement remains crucial. In this regard, a mixed linker type zirconium metal organic framework (Zr-MOF) with terepthalic acid based ditopic linkers were utilized to design a single component photocatalyst through single step solvothermal method to utilize photons from visible light illumination towards hydrogen energy (H2) production and Tetracycline Hydrochloride (TCH) degradation. The one pot synthesized mixed linker based Zr-MOF displays visible light absorption through band gap tuning, superior exciton segregation and oxygen vacancy that cumulatively supports the enhancement in the photocatalytic output with respect to their pristine counterparts. Additionally, the X-ray photoelectron spectroscopy, optical and electrochemical studies strongly reinforces the above claims. The prepared mixed linker Zr-MOF showed superior photocatalytic H2 evolution performance of 247.88 µmol h−1 (apparent conversion efficiency; ACE = 1.9%) that is twice than its pristine Zr-MOFs. Moreover, in TCH degradation, the mixed linker MOF displays an enhanced efficacy of 91.8 % and adopts pseudo-first order type kinetics with a rate constant value of 0.032. Typically, the active species participating for the TCH photo-degradation follows the order of hydroxyl (OH.) < superoxide (O2.-) radicals. Consequently, the mixed linker Zr-MOF could be effectively used as a robust photocatalyst exhibiting boosted TCH degradation and H2 production.