Abstract

Hydrolysis of N-vinyl-2-oxazolidone(NVOx) was studied in the presence of various acids at the different pH. Solvent effects on the hydrolysis were investigated. lt was concluded that there is a large contribution of hydrophobic or hydrogen bonding interaction between NVOx and acids.The rate of hydroiysis isproportional to t he first order of NVOx and acids concentration, respectively. Activation energies and activation entropy change in this hydrolysis were ca.16kcal/mol and -24 N-27 e.u., respectively.Further, hydrolysis of N-vinylpyrrolidone(NVPy) was examined and it was found that the rate of hydrolysis of NVPy waslarger than NVOx.

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