Abstract
Various hybrid catalysts prepared by mechanically mixing Pt(Pd) promoted oxides (Al2O3, SiO2) and an acidic component (RE-FAU, H-Beta zeolites and SO4/ZrO2 solid Superacid) were studied in C6–C14 n-alkane skeletal isomerization. The hybrid catalysts exhibited high activity and selectivity in paraffin isomerization. The enhancement in the activity of hybrid catalysts as compared to individual components was rationalized in terms of spillover of reactive species between metal promoted oxide systems and acidic sites.
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