Hydrogen separation via forming hydrate in W/O emulsion

Abstract

In this work, hydrogen was separated from CH4/H2 gas mixtures via forming hydrate in water in oil emulsion. Aqueous phase is the aqueous solution of 3.0wt% Span 20. Oil phase is the mixture of diesel and cyclopentane (CP) with a CP concentration of 50vol%. Span 20 was used to disperse water or hydrate in diesel to form emulsion or hydrate slurry. CP was used to moderate the hydrate formation condition. Two H2/CH4 feed gas mixtures, containing 68.0mol% and 84.7mol% of hydrogen respectively, were prepared. A series of experiments were performed with respect to two feed gas mixtures to investigate the influences of temperature, pressure, and water cut upon the separation efficiency. Our experimental results show that suitable low temperature (274.15K or so), high pressure (5–6MPa), and water cut around 20vol% are favorable for H2 separation. The highest separation factor of H2/CH4 reaches 49. After a two-stage separation at 274.15K, the concentration of H2 in gas phase could be increased from 68mol% to more than 92mol% and nearly 90% of H2 can be recovered in gas phase.