Hydrogen isotope permeation through interfaces and permeability of tungsten layers

Abstract

The estimation of the hydrogen isotope flux through a fusion reactor wall component is important for the material selection and in order to guarantee a safe and economical reactor operation. Since the permeation flux through a component cannot be measured directly, due to the large size of such a component, the deuterium permeability of various fusion materials were investigated in the last years. In order to investigate, if an interface, meaning a change of materials in a component, has an influence on the permeation flux, combined material systems in laboratory scale are studied. The combined materials systems are produced by applying a thin W or Cu layer on a polished bulk steel or CuCrZr substrates by magnetron sputter deposition. In a previous study (Houben et al., 2022), the combined material system of Cu coated steel was investigated. The conclusion was that the interface has a minor influence on the permeation flux compared to the large influence of the layer microstructure. In order to investigate, if the minor influence of the interface is valid in general, the systems W coated steel and CuCrZr are studied in this publication. By heating the substrate during W sputter deposition, a crack-free W layer is produced and crack propagation in the W layer at elevated temperature is prevented. The W layer permeabilities are obtained for both W coated substrates and are similar, but compared to the W bulk permeability from literature the W layer permeabilities are several orders of magnitude larger.The main conclusion from these studies is that in all investigated combined material systems the influence of the interface on the permeation flux is minor compared to the large influence of the microstructure. Therefore, for a reliable estimation of the permeation flux through a fusion reactor component it is crucial to characterize the applied materials. Especial for coatings the measurement of the layer permeability is important, since the layer permeability of a material can be very different compared to the permeability of a bulk material.