Abstract
We discuss the influence of site occupancy on the absorption of the hydrogen isotopes H and D in thin V(001) layers. By growing V(001) under biaxial compressive strain in Fe/V(001) superlattices, the hydrogen (H as well as D) is forced to reside exclusively in octahedral (${\mathrm{O}}_{z}$) sites, even at the lowest concentrations. A weakening of the isotope effects is observed when hydrogen resides in octahedral as compared to tetrahedral sites.
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