Abstract
The radiolysis of ethylene-d2 and C2H4–C2D4 mixtures has been investigated in the gas, liquid, and solid phases. The data indicate that hydrogen may be formed by two distinct molecular-elimination processes: CH2CH2→CH2C+H2 and CH2CH2→CH≡CH+H2. The effect of xenon and pressure on the yields of H2, HD, and D2 in the gas-phase radiolysis of CH2CD2 has been investigated. The results for the (2P1)Hg-sensitized and the 1237 A-photochemical decomposition have been compared with those for radiolysis.
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