Abstract
Abstract The interactions of ascorbic acid (AA) with urea were investigated by using the cyclic voltammetry, density functional theory, atoms in molecules and natural bond orbital analyses. The experimental and theoretical results show that the hydrogen bonds are formed between AA and urea, wherein the mainly interaction sites are the hydrogen atoms on enediol of AA and the oxygen atom on carbonyl of urea. The electrochemical behavior of AA was significantly affected by above interactions.
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