Hydrogen absorption performance of a novel cylindrical MH reactor with combined loop-type finned tube and cooling jacket heat exchanger

Abstract

A novel cylindrical metal hydride (MH) reactor with loop-type finned tube and jacket heat exchanger was proposed in this work. This MH reactor is expected to possess high performance due to the enhanced heat transfer, compact structure and good gas tightness. A three-dimensional multi-physical model for hydrogen absorption was presented to investigate the evolutions of temperature and concentration in the MH bed, as well as the mean reaction rate of hydrogen absorption process. The effects of different fin configurations on the performance of the proposed MH reactor were also examined. It was indicated that the evolution curve of the mean reaction rate for the whole hydrogen absorption process can be divided into two stages. The reaction rate in the first stage is mainly dependent on the initial conditions (i.e., temperature and gas pressure) of MH bed, whereas the second stage is mainly influenced by the heat dissipation from MH bed to cooling fluid. For the proposed MH reactor, the total charging time for reaching 90% hydrogen saturation can be decreased by 56.8% and 81.9% as compared with that for cylindrical MH reactor with finned double U-shape tube heat exchanger and cylindrical MH reactor with finned single-tube heat exchanger, respectively. Also, it was found that the interlaced layout design of inner and outer fins can improve the uniformity of the temperature distribution inside the MH bed as compared with the parallel layout configuration. Besides, it was showed that increasing the number of fins with keeping the total fin volume constant, the absorption performance of the reactor can be improved.