Abstract
The effect of inorganic ammonium salts which contain group VIB metals of the periodic table (ammonium chromate, ammonium dichromate, ammonium molybdate and ammonium tungstate) as additives on the catalytic performance of Rh catalysts for the hydroformylation of C 8-olefins and 1-dodecylene has been investigated. Modification of rhodium with ammonium salts could increase the yield of aldehydes in the hydroformylation of the olefins without phosphine oxide or phosphine ligands and also decrease Rh loss in the distillation process for the separation of the products from the catalyst.
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