Hydrodesulfurization of diesel in a slurry reactor

Abstract

The need for more complete removal of sulfur from fuels is due to the lower allowable sulfur content in gasoline and diesel, which is made difficult by the increased sulfur contents of crude oils. This work reports an experimental study on the hydrodesulfurization (HDS) of diesel in a slurry reactor. HDS of straight-run diesel using a NiMoS/Al 2O 3 catalyst was studied in a high-pressure autoclave for the following operating conditions: 4.8–23.1 wt% catalyst in the reactor, 320–360 °C, 3–5 MPa pressure, and 0.56–2.77 L/min hydrogen flow rate. It was found that the reaction rate was proportional to the catalyst amount and increased with temperature, pressure and hydrogen flow rate. The reaction kinetics for the HDS reaction in the slurry reactor was obtained. As compared with HDS in a fixed bed reactor, HDS in a slurry reactor is promising because of the uniform temperature profile, high catalyst efficiency, and online removal and addition of catalyst.