Abstract
The effects of two different low calcium fly ashes on the hydration of ordinary Portland cement (OPC) pastes containing 50wt.% of fly ash were investigated over a hydration time of 550days. The results were compared with a reference blend of OPC containing 50wt.% of inert quartz powder allowing the distinction between "filler effect" and pozzolanic reaction.Until 2days, no evidence of fly ash reaction was measured and its influence on the hydration is mainly related to the “filler effect”. From 7days on, the effects of the pozzolanic reaction were observed by the consumption of portlandite, the change of the pore solution chemistry, the formation of a presumably water-rich inner hydration product and the change of the C–S–H composition towards higher Al/Si ratio compared to the C–S–H of neat OPC. Additional strength due to the pozzolanic reaction developed after 28days of hydration.
Published Version
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