Abstract
High-resolution transmission electron microscopy has been applied to the characterization of the Rh/Sm 2O 3 system. The comparison between Rh/CeO 2 and Rh/Sm 2O 3 catalysts suggests a model of behavior that would be operative for metals supported on rare-earth sesquioxides. The model assumes that a significant dissolution of the support takes place during the impregnation step. As a consequence, the metal would be present in a highly dispersed state after the drying process, forming a mixed phase with the support material, which explains why metal crystallites are only observed after reduction followed by heat treatment at high temperature.
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