Abstract

High-resolution transmission electron microscopy has been applied to the characterization of the Rh/Sm 2O 3 system. The comparison between Rh/CeO 2 and Rh/Sm 2O 3 catalysts suggests a model of behavior that would be operative for metals supported on rare-earth sesquioxides. The model assumes that a significant dissolution of the support takes place during the impregnation step. As a consequence, the metal would be present in a highly dispersed state after the drying process, forming a mixed phase with the support material, which explains why metal crystallites are only observed after reduction followed by heat treatment at high temperature.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call