Hot Set Characterization of Electron Beam Irradiated-Copper (II) Oxide Added LDPE Composites under Acidic Aging

Abstract

In this research study, the effect of aging duration time and electron beam irradiation dosages on the hot set results of copper (II) oxide added LDPE composites have been investigated. The addition of copper (II) oxide particles in LDPE matrix has significantly reduced the formation of crosslinking networks in LDPE matrix by blocking the mobility of free radicals generated by electron beam irradiation. At lower irradiation dosages (< 100 kGy), all the copper (II) oxide added LDPE composites were immediately failed the hot set test when subjected to static load of 20 N/cm2 under high temperature. Besides, the occurrence of copper (II) oxide particles in LDPE matrix also reduced the matrix continuities of copper (II) oxide added LDPE composites and caused the matrix resistance ability of LDPE matrix to be decreased. The increasing of irradiation dosages has significantly delayed the failing time of all LDPE composites when under static load at high temperature. This is because the increasing of electron beam irradiation could further induce the generation of free radicals to form higher degree of crosslinking networks in LDPE matrix. At higher irradiation dosage up to 250 kGy, the pristine LDPE was observed able to withstand the applied static load under high temperature more than 15 minutes. This is due to higher degree of crosslinking networks formed in LDPE matrix could effectively restrict the mobility of LDPE chains under static load and thus delay the failing of sampels. When the aging duration time increased from 4 days to 14 days, the resistance ability of all LDPE has been significantly weakened due to the occurrence of chain scissioning process in LDPE matrix by delaying the failing time of samples.