Hollow porous magnetic/magnetic heterostructured CoFe/defective spinel microspheres template-free synthesis and effective modulation of microwave absorption performance

Abstract

To create a spinel ferrite with excellent performance for electromagnetic (EM) wave absorption in the low frequency range of 4–6 GHz, compositions based on Co0.75Zn0.125Fe0.125Fe2O4 (CZF–1) and Co0.5Zn0.25Fe0.25Fe2O4 (CZF–2) with multiple elements substituted for A sites were synthesized by using solvothermal method. Hollow porous magnetic/magnetic heterostructure microspheres (HHMs) of CZF–A1 and CZF–A2 with multiple interfaces were prepared by hydrogen–thermal reduction of CZF–1 and CZF–2, and their unique structure and EM absorption properties were investigated in detail. The widest effective absorption bandwidth (EAB) of CZF–A1 and CZF–A2 was 4.1 GHz (13.6–17.7 GHz) and 3.7 GHz (8.0–11.7 GHz) for a corresponding thickness of 1.4 mm and 2.0 mm, respectively. In addition, the minimum reflection loss (R.Lmin) of CZF–A1 and CZF–A2 reached –49.1 dB (at fm = 13.4 GHz) and –45.0 dB (at fm = 4.2 GHz) at a thicknesses of 1.6 mm and 3.7 mm, respectively. More specifically, in the low frequency region of 4–6 GHz, CZF–A1 and CZF–A2 exhibited excellent EM wave absorption due to the effective regulation of their natural resonance frequency. The EM wave absorption frequency band of CZF–A1 and CZF–A2 samples was able to completely cover the 4–6 GHz frequency region for at coating thickness of CZF–A1 and CZF–A2 was only 3.5 mm and 3.3 mm respectively, and their R.Lmin reached –36.5 dB and –22.6 dB. Moreover, the absorption mechanisms of CZF–A1 and CZF–A2 including magnetic resonance, eddy current loss, interfacial polarization and dipole polarization were also investigated in detail. This research provides new insights and guidance for the development of spinel ferrite-based EM absorbers for high efficiency EM wave absorption in the low frequency (4–6 GHz) region.