Bayberry-like bimetallic CoNi-MOF-74 derivatives/MXene hybrids with abundant heterointerfaces toward high-efficiency electromagnetic wave absorption

Abstract

The flourishing development of electronic devices and radar detection technologies necessitates the urgent creation of high-efficiency electromagnetic wave (EMW) absorption materials with expansive absorption bandwidths. Although MXene has garnered significant interest in the domain of EMW absorption due to its tunable dielectric properties and structural designability, its high permittivity often results in poor impedance matching and a single loss mechanism, which makes it difficult to realize optimal EMW absorption capabilities. In this work, CoNi bimetallic metal–organic frameworks (MOFs) derived bayberry-like magnetic porous carbon (CoNiMPC)@carbon nanotubes (CNTs)/MXene (CNCM) hybrids were initially synthesized via simple solution precipitation, thermal treatment, and electrostatic self-assembly strategy. As anticipated, excellent EMW absorption characteristics were achieved by adjusting the ratio of CoNiMPC@CNTs and MXene. Multi-heterointerfaces consisting of zero-dimensional porous carbon, one-dimensional carbon nanotubes, and two-dimensional (2D) MXene, electrical/magnetic coupling effects, and polarization loss induced by abundant heterointerfaces endow the prepared CNCM hybrids with high-performance EMW absorption. Notably, the CNCM-7 hybrid material exhibits a minimum reflection loss (RLmin) of − 65.3 dB at 6.8 GHz with a mere 2.7 mm thickness and an effective absorption bandwidth (EAB, RL < −10 dB) of 5.0 GHz at a thickness of 1.27 mm. This study proposes a unique viewpoint and approach towards the design and preparing high-performance MXene-based EMW absorption materials.