Abstract

AbstractCopolymers of acrylonitrile and vinylchloride (molar ratio ACN : VC = 44.5 : 55.5) were synthesized by continuous emulsion polymerization. Their sequence distribution was studied by 13C‐NMR‐spectra at 90.52 MHz. Three different methylene carbon regions were attributed to diads of the type VCVC,VCACN and ACNACN. The experimentally determined diad distribution was in good agreement with the calculated diad distribution, using reactivity ratios of rACN = 3.6 and rVC = 0.05.

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