Abstract

High-temperature durable mirrors based on a protected silver sputter coating are attractive for secondary reflector applications in concentrated solar thermal power plants. In this paper, silver films are deposited by high-power impulse magnetron sputtering (HiPIMS) and standard direct current (DC) magnetron sputtering, either as exposed discretely deposited films or in-sequence-deposited thin film systems, where the silver is protected and embedded between adhesion and barrier layers. The unprotected silver films and equivalent protected silver thin film systems are compared and characterized as deposited and after 400 °C oven temperature exposure. The reflectance is measured and grazing incident X-ray diffraction (GIXRD) and scanning electron microscopy (SEM) pictures were taken. The HiPIMS silver film, sputtered with a peak current of 200 A and an approximately equivalent average power density to the DC magnetron sputtered silver, exhibits higher reflectance (and conductivity). Increasing the power density further, yields silver films with lower reflectance, correlating to a reduced grain size. In the protected silver film system, the reflectance does not improve, due to the presence of a less reflective top adhesion layer. The protected film system, with the 200 A HiPIMS, is, however, more durable at 400 °C than the DC magnetron sputtered equivalent.

Highlights

  • Concentrated solar power (CSP) systems generate solar power by using mirrors or lenses to concentrate a large area of sunlight, or solar thermal energy, onto a smaller area

  • A secondary reflector which is installed adjacent to the solar tower or linear Fresnel collector receiver can improve the optical efficiency of the system considerably as well as reducing its cost by [2]:

  • For the solar power tower, the high temperatures evolve mainly due to the amount of irradiance that is being absorbed by the mirror, and to a lesser extent due to convective heat exchange with its surrounding

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Summary

Introduction

Concentrated solar power (CSP) systems generate solar power by using mirrors or lenses (primary concentrators or reflectors) to concentrate a large area of sunlight, or solar thermal energy, onto a smaller area (the receiver). A secondary concentrator reflects the sunlight coming from the primary concentrators onto the absorbing receiver. They ensure the gathering and redirecting, and in some applications further concentration and focusing, of the solar beams towards the absorber. A secondary reflector which is installed adjacent to the solar tower or linear Fresnel collector receiver can improve the optical efficiency of the system considerably as well as reducing its cost by [2]: . For the solar power tower, the high temperatures evolve mainly due to the amount of irradiance that is being absorbed by the mirror, and to a lesser extent due to convective heat exchange with its surrounding.

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