Abstract

The emission spectrum of the B 3Π g - A 3Σ u + system of the 15N 2 molecule was recorded between 3500 and 12 500 cm −1 with a high-resolution Fourier spectrometer. Twelve bands with 0 < v′ < 5 and 0 < v″ < 9 are analyzed. The molecular parameters of the B 3Π g and A 3Σ u + states are obtained by a complete fitting procedure. Derived values of equilibrium constants are deduced; the Franck-Condon factors are calculated for the B- A system of 15N 2.

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