High-performance large-area blade-coated perovskite solar cells with low ohmic loss for low lighting indoor applications

Abstract

Emerging hybrid organic–inorganic perovskites with superior optoelectronic property demonstrate promising prospect for photovoltaic (PV) applications, in particular for low-lighting indoor applications e.g. within internet of things (IoT) networks or low-energy wireless communication devices. In order to prepare devices with high power output under low-illumination conditions, scalable fabrication techniques are preferred for large-area perovskite solar cells. In additions, one of the key parameters to achieve high-efficiency large-area perovskite solar cells is to minimize the ohmic loss to further boost the solar cell efficiency. Herein, a one-step blade-coating method assisted by hexafluorobenzene (HFB) was developed to deposit dense, large-area smooth and high-quality perovskite films with low ohmic loss. The as-fabricated devices demonstrated power conversion efficiency (PCE) of 20.7% (area of 0.2 cm2) and 16.5% (1 cm2), respectively, under standard (AM 1.5G) illumination conditions. Besides, the large-area (1 cm2) devices demonstrated a remarkable PCE of ∼ 33.8% and ∼ 30.0% under 1000 lx and 100 lx illumination provided by white light-emitting diode (LED) lamp, respectively. We exhibited a series-connected stack of large-area (totally active area ∼ 4 cm2) perovskite photovoltaic device powering up a LED under common indoor environment as an indoor self-power indicator lamp. The analysis using a single diode model suggests that the high performance of the large-area devices under low-lighting indoor conditions is highly associated with the largely reduced ohmic losses, which particularly indicate that the perovskite films by a facile and scalable blade-coating method. The presented scalable approach paves the way to designing high-performance perovskite solar cells for a variety of emerging indoor PV applications.