Abstract

Stretchable and lightweight polymer composite material possessing tunable microwave absorption (MA) properties under thermal radiations remain a significant challenge. Here, we proposed a facile strategy to fabricate stretchable, magnetic composite skeletons by incorporating the tadpole-like CNTs@Fe3O4 nanoparticles into self-foaming polyurethane (PU) matrix and the electromagnetic responsive of CNTs@Fe3O4/PU composite foams with different CNTs contents under heating−cooling cycle in a temperature range of 253 −333 K were carefully investigated. Enhanced complex permittivity and shifting peak frequency were observed at elevated temperatures. For instance, the 70-CNTs@Fe3O4/PU sample with 15 wt% loading content at 333 K exhibits excellent MA properties including a minimum reflection loss (RLm) of −66.9 dB and ultrabroad effective frequency bandwidth (RL ≤ −20 dB) of 9.98 GHz at the thickness of 1.58−3.37 mm. Meanwhile, great recoverability in terms of RL-f profile was achieved in the process of thermal cooling back to 253 K. Such adjustable MA property was attributed to the well-matched impedance and dramatic attenuation ability, benefiting from the temperature-dependant electrical conductivity, abundant interfacial polarization and interior microcellular structures. Besides, the rising temperature increased the sample elongation and electrical conductivity with a slight sacrifice of maximum tensile strength. This stretchable PU skeleton with a unique assembly of CNTs and Fe3O4 nanoparticles are expected to be promising candidates as smart absorbers for application in the harsh environments.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call