Highly Stable CsSnCl3 Quantum Dots Grown in an Ionic Liquid/Gelatin Composite System through an In Situ Method.

Abstract

Lead halide perovskite quantum dots (QDs) are controversial due to their high lead content. Tin, a low-toxic element with an outer electronic structure similar to that of Pb, becomes a strong candidate for preparing lead-free perovskite QDs. However, tin-based perovskite QDs, especially CsSnCl3 QDs, exhibit poor environmental stability. Herein, we proposed an strategy for highly stable CsSnCl3 QDs using an ionic liquid as a solvent and antioxidant and gelatin as a multidentate ligand and coating material through an in situ method ([AMIM]Cl/gelatin-QDs). The results showed that the abundant active groups of gelatin served as the nucleation growth center for QDs and further passivated QDs. At the same time, the long molecular chain of gelatin can coat the QDs to isolate the environment and fully protect QDs, and the size of QDs grown in gelatin was 5-10 nm. In addition, the oxidation resistance of ionic liquids and the halogen-rich environment formed also played an important role. Even if [AMIM]Cl/gelatin-QDs were treated with water and ultraviolet light simultaneously, its remaining fluorescence intensity was still above 60% within 72 h. Meaningfully, QDs endowed the composite system mildew resistance, which can resist the erosion of gelatin by molds, thereby realizing the system's long-term protection toward CsSnCl3 QDs.