Abstract
MOF-based sensors capable of effectively and stably detecting toxic species in water have attracted huge attention in terms of improving environmental monitoring levels and water quality. Combining the flexibility of structure and modifying of pore surface, a multiwalled divider installation (MWDI) strategy is proposed and used for property enhancement. We herein report three metal-organic frameworks (MOFs) 1-3 based on a C3 symmetry organic phosphonic ligand with topology increased from 3,6-connected to 3,8-connected. Among them, MOFs 1 and 2 with remaining binding sites and large pores display lower luminescence response to Co2+ than does the applying standard. Guided by the MWDI strategy, 3 with high rigid framework and triple molecular installer divided rhombic pore was achieved under top-down topological analysis as anticipated, which endows high sensitivity and rapid response to Co2+, contributed by the synergy from free activated sites and appropriate pore and molecular dividing effect. Particularly, the high stability of 3 in boiling solvent and acid/base solutions has been evidenced and explained by structural robustness and kinetic inertness. Moreover, 3 shows excellent detection ability toward trinitrophenol (TNP) over other aromatic analytes in water, attributing to the predomination of energy transfers. Of note is that the used framework can be in situ regenerated into a fresh one. That provides a promising strategy to prepare effective and economic luminescent sensors in a predictable way for property modification.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.