Abstract
A rare, robust microporous lanthanide metal-organic framework with 1D honeycomb-type channels is presented. Excellent adsorption capabilities for N(2), H(2), and CO(2) and significant selective sorption of CO(2) over N(2) and CH(4) were observed. Moreover, the guest-dependent luminescent behavior of these lanthanide materials shows a potential use for the sensing of small-molecule pollutants such as benzene and acetone.
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