Abstract
The Shpol'skii method yields quasilinear spectra of exo-naphtho [b:3,4] tricyclo [4.2.1.0. 2,5] nonane 5 in n-hexane at 5 K. This result is discussed with reference to the “key and hole” rule. Highly resolved spectra of the 2,3-naphthoquinodimethane derivative 4 are obtained by photolysis of 5. The results are comparable with those of o-durylene 3.
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