Highly Position- and Enantioselective Catalytic Epoxidation of Polyolefins Mediated by a Chiral Mn Complex, Including a One-Step Conversion of Squalene to the (S)-2,3-Epoxide, a Precursor of Natural Steroids and Terpenoids.

G Sudhakar Reddy,E J Corey

doi:10.1021/jacs.4c16570

Highly Position- and Enantioselective Catalytic Epoxidation of Polyolefins Mediated by a Chiral Mn Complex, Including a One-Step Conversion of Squalene to the (S)-2,3-Epoxide, a Precursor of Natural Steroids and Terpenoids.

G Sudhakar Reddy, E J Corey

https://doi.org/10.1021/jacs.4c16570

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Journal: Journal of the American Chemical Society

Publication Date: Jan 6, 2025

#Polyolefinic Substrates #Mn Complex #Precursor Of Terpenoids #Precursor Of Steroids #Natural Terpenoids #Mild Conditions #Synthesis Of Ligand #Application Of Complex #Chiral Complex #Chiral Ligand

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Reported herein is the synthesis of a novel chiral dicarboxylic ligand for Mn(II) and the application of the Mn complex to the highly enantio- and position-selective epoxidation of C═C under mild conditions, even with polyolefinic substrates. A stereomechanistic basis for asymmetric induction is suggested.

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Highly Position- and Enantioselective Catalytic Epoxidation of Polyolefins Mediated by a Chiral Mn Complex, Including a One-Step Conversion of Squalene to the (S)-2,3-Epoxide, a Precursor of Natural Steroids and Terpenoids.