Abstract

Green phosphorescent inverted top-emitting organic light-emitting diodes with high current efficacy and luminance are demonstrated on glass and polyethersulfone (PES) substrates coated with polyethylene dioxythiophene-polystyrene sulfonate (PEDOT:PSS). The bottom cathode is an aluminum/lithium fluoride bilayer that injects electrons efficiently into an electron transport layer of 1,3,5-tri(m-pyrid-3-yl-phenyl)benzene (TpPyPB). The cathode is found to be highly sensitive to the exposure of trace amounts of O2 and H2O. A high current efficacy of 96.3 cd/A is achieved at a luminance of 1387 cd/m2 when an optical outcoupling layer of N,N′-Di-[(1-naphthyl)-N,N′-diphenyl]-(1,1′-biphenyl)-4,4′-diamine (α-NPD) is deposited on the anode.

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