Abstract

AbstractHybrid Ni@g‐C3N4‐catalyzed highly chemoselective reduction of nitroarenes with high turnover frequency has been demonstrated using NaBH4 as source of hydrogen. Here, g‐C3N4 provides excellent stability to Ni(0) nanoparticles on its nitrogen rich surface and also facilitates the dissociation of NaBH4 resulting formation of active Νi‐H+ and Νi‐H‐ via cooperative effect.

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