Highly effective removal of Pb2+ in aqueous solution by Na-X zeolite derived from coal gangue.

Abstract

The present study aimed to synthesize Na-X zeolite from coal gangue powder (CGP) via the alkali fusion hydrothermal method. The optimal synthetic conditions were investigated, the mass ratio of CGP/NaOH(s) was 1:1.25, and crystallization reaction time was 12h. X-ray powder diffraction, scanning electron microscopy energy-dispersive X-ray spectrum, and Fourier transform infrared spectrometer techniques were used to test the properties of resultant zeolite product, which was highly identical to that of commercial zeolite. The efficiencies of the synthetic zeolite for Pb2+ adsorption were analyzed on factors including solution pH, adsorbent dosage, temperature, and contact time. Compared with the pseudo-first-order, Elovich, Freundlich, and Temkin models, the pseudo-second-order and Langmuir models were fitted more satisfactorily with the dynamic data and adsorption equilibrium data, respectively. The maximum Pb2+ adsorption capacity of synthetic zeolite (457mg/g) could be reached when the pH, contact time, temperature, and initial Pb2+ concentration was 6, 40min, 45°C, and 200mg/L. The adsorption capacity was higher than many of the natural and synthetic zeolites reported in previous literature.